The Amazing Spider-Man Vol. 1 Issue 201

"Man-Hunt!"

Spider-Man finds the Punisher shooting up a bunch of criminals. Setting up his camera, Spider-Man gets involved and is relived that the Punisher is only using mercy bullets and hasn't actually killed anyone yet. After the carnage, Spider-Man asks the Punisher what he's up to and the Punisher informs him that he intends to kill the drug dealer Lorenzo Jacobi